The Münck Group

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up to 1979     1980 - 1989     1990 - 1999     2000 - 2009   2010 - Present

267     Xue, G.; De Hont, R.; Münck, E. ; Que, L., Jr. “ Million-fold Activation of the [Fe2(u-O)2] diamond core for C-H Bond Cleavage” Nature Chem. 2010, 2, 400-405.

268     Mukherjee, A.; Cranswick, M.; Chakrabarti, M.; Paine, T.; Fujisawa, K.; Münck, E.; Que, L. "Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective" Inorg. Chem. 2010, 49, 3618-28.

269     Chakrabarti,M.; Deng, L. Holm, R. H.; Münck, E.; Bominaar E. L. “The Modular Nature of Edge-bridged Double CubanesInorg. Chem. 2010, 49, 1647-50.

270     Stoian, S.; Paraschiv, C.; Kyritsakas, N.; Lloret, F.; Munck, E.; Bominaar, E.; Andruh, M. "Mössbauer, EPR, and magnetic susceptibility studies on members of a new family of cyano-bridged 3d-4f complexes. Demonstration of anisotropic exchange in a Fe-Gd complex" Inorg. Chem. 2010, 49, 3387-3401.

271     De Hont, R. F.; Xue, G.; Hendrich, M. P. ; Que, L. ; Bominaar, E. L. ; Münck, E. "Mössbauer, EPR and DFT Studies of two Synthetic u-oxo bridged FeIVFeIII S = ½ Complexes containing a high-spin FeIV=O site: 57Fe hyperfine interactions and Exchange couplings” Inorg. Chem. 2010, 49, 8310-22.

272     England, J.; Guo, Y.; Farquhar, E.R.; Young, V. J.; Munck, E.; Que, L. “The Crystal Structure of a High-Spin OxoIron(IV) Complex and Characterization of Its Self-Decay Pathway” J. Am. Chem. Soc. 2010, 132, 8635-44.

273      Holmes-Hampton, G.; Miao, R.; Garber-Morales, J.; Guo, Y.; Münck, E.; Lindahl, P. "A Nonheme High-Spin Ferrous Pool in Mitochondria Isolated from Fermenting Saccharomyces cerevisiae" Biochemistry 2010, 4, 4227-34.

274     Garber-Morales, J. Holmes-Hampton, G. P.; Miao, R.; Guo, Y.; Münck, E.; Lindahl. P. A. “Characterization of Iron in Mitochondria Isolated from Respiring and Fermenting Yeast” Biochemistry 2010, 49, 5436-44.

275     Makris, T. A. ; Chakrabarti, M.; Münck, E.; Lipscomb, J. D. “A family of diiron monooxygenases catalyzing amino acid beta hydroxylation in antibiotic biosynthesis” Proc. Natl. Acad. Sci. USA 2010,107, 15391-96.

276     Mbughuni, M.; Chakrabarti , M.; Title: Hayden , J.; Bominaar, E. ; Hendrich, M, Münck, E.; Lipscomb, J. "Trapping and spectroscopic characterization of an FeIII -superoxo intermediate from a non-heme mononuclear iron-containing enzyme", Proc. Natl. Acad. Sci. USA 2010, 107, 16788-93.

277     McDonald, A.; Bukowski, M.; Farquhar, E.; Jackson, T.; Koehntop, K. ; Seo, Mi S.; De Hont, R.; Stubna, A.; Halfen, J.; Münck, E.; Nam, W.; Que, L. "Sulfur versus Iron Oxidation in an Iron-Thiolate Model Complex" J. Am. Chem. Soc. 2010, 17118-29.

278     Company, A.; Prat, I.; Frisch J.R.; Ruben Mas Ballesté,R.M.; Güell M.; Juhász G.; Ribas, X.; Eckard Münck,E.; Luis, J. M.; Que, Jr., L.; Miquel Costas M. “Modelling the cis-oxo-labile binding site motif of non-heme iron oxygenases. Water exchange and remarkable oxidation reactivity of a novel non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand”, Chem. Eur. J. 2010, in press.

279     Martinho, M.; Münck, E. 2010, "57Fe Mössbauer Spectroscopy in Chemistry and Biology" in Physical Inorganic Chemistry" A. Bakac, ed, Wiley, Inc.

280     Münck, E.; Bominaar, E. L. 2011 “Mössbauer Spectroscopy of Biological Systems” in “The Rudolf Mössbauer Story”, G. M. Kalvius and P. Kienle (editors), Springer Verlag, in press.

281     Bruijnincx PC, Buurmans IL, Huang Y, Juha´sz G, Viciano-Chumillas M, Quesada M, Reedijk J, Lutz M, Spek AL, Münck E, Bominaar EL, Klein Gebbink RJ "Mono- and Dinuclear Iron Complexes of Bis(1-methylimidazol-2-yl)ketone (bik): Structure, Magnetic Properties, and Catalytic Oxidation Studies." Inorg. Chem. 2011, 19, 9243-55.

282     England, J.; Guo, Y.; Van Heuvelen, K. M. Cranswick, M.A., Rohde, G. T.; Bominaal E. L.; Münck, E. Que, L. Jr "A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site." J. Am. Chem. Soc. 2011, 133, 11880-83.

283     Mbughuni, M.; Chakrabarti, M.; Hayden, J.A.; Meier, K. K. , Dalluge, J.J.; Hendrich, M.P.; Münck, E.; Lipscomb, J.D. "Oxy-Intermediates of Homoprotocatechate 2,3 Dioxygenase: Facile Electron Transfer between Substrates" Biochemistry, 2011, 50, 10262-74.

284     Li, F.; Chakrabarti, M.; Dong, Y.; Kauffmann, K.; Bominaar, E. L.; Münck, E.; Que, Jr., L. "Structural, EPR, and Mössbauer characterization of (μ-alkoxo)(μ-carboxylato)diiron(II,III) model complexes for the active sites of mixed-valent diiron enzymes" Inorg. Chem. 2012, 51, 2917-29.

285     Van Heuvelen, K. M.; Fiedler, A. T.; Shan, X.;  De Hont, R. F.; Meier, K. K.; Bominaar, E. L.; Münck, E.;  Que, Jr., L. "An [O=FeV=NR]+ Center Formed by One-Electron Oxidation of an Oxoiron(IV) Complex" Proc. Natl. Acad. Sci. 2012, 109, 11933-38.

286     Fleischhacker A. S.; Stubna, A.; Hsueh, K. L.; Guo, Y.; Teter, S. J.; Rose, J. C.; Brunold, T. C.; Markley, J. L.; Münck, E.; Kiley, P.J. "Characterization of the [2Fe-2S] Cluster of E. coli Transcription Factor IscR" Biochemistry 2012, 51, 4453-62.

287     McDonald, A. R.; Van Heuvelen, K. M.; Guo, Y.; Bominaar, E. L.; Münck, E.; Que, Jr., L. "Characterization of a Unique Thiolato-Iron(III)-Peroxide Complex" Inorg. Chem. 2012, 51, 2917-29.

288    Cranswick, M. A.; Meier, K. K.; Shan, X.  Stubna, A.; Kaizer, J.; Mehn, M. P.; Münck, E.; Que, Jr., L. "Protonation of a peroxodiiron(III) complex and conversion to a diiron(IV) intermediate: Implication for proton assisted O-O bond cleavage in non-heme Diiron enzymes"  Inorg. Chem. 2012, 51, 10417-26.

289    Mbughuni, M. M.; Meier, K. K.; Münck, E.; Lipscomb, J. D. "Substrate-Mediated Oxygen Activation by Homoprotocatechuate 2,3-Dioxygenase: Intermediates Formed by a Tyrosine 257 Variant" Biochemistry  2012, 51, 8743-54.

290    Banerjee, R.; Meier, K.K.; Münck, E.; Lipscomb, J.D.  "Intermediate P* from Soluble Methane Monooxygenase Contains a Diferrous Cluster" Biochemistry 2013, 52, 4331-42.

291    Li, F.; Van Heuvelen, K.; Meier, K. K.; Münck, E.; Que, Jr., L. "Sc3+-triggered oxoiron(IV) formation from O2 and its nonheme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate" J. Am. Chem. Soc. 2013, 135, 10198-201. 

292    Stoian, S. A.; Xue, G.; Bominaar, E. L.; Que, Jr., L.; Münck, E.; " Spectroscopic and theoretical investigation of a complex with a [O=FeIV-O-FeIV=O] core related to methane monooxygenase intermediate Q" J. Am. Chem. Soc. 2014, Jan 14.

294    Oloo, W. N.; Meier, K. K.; Wang, Y.; Shaik, S.; Münck, E.; Que, Jr., L. "Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations” Nature Communications  2014, 5, 3046-3054.

295    England, J.,  Bigelow, J. O.;  Van Heuvelen, K. M.; Farquhar, E. R.;  Martinho, M.;  Meier, K. K.; Frisch, J. R.; Münck, E.; Que, Jr., L. "An Ultra-Stable Oxoiron(IV) Complex and its Blue Conjugate Base" , Chem. Sci., 2013, 5, 1204-1215.

296    Chiang, C.-W., Kleespies, S.T., Stout, H.D., Meier, K.K., Li, P.-Y., Bominaar, E.L. Que, Jr., L., Münck, E. and Lee, W.Z. "Characterization of a Paramagnetic Mononuclear Nonheme Iron-Superoxo Complex" J. Am. Chem. Soc. 2014, 136, 10846-49.

297    Liu, J.;  Meier, K.K.; Tian, S.;  Zhang, J. Guo, H.; Schulz, C.E.; Robinson, H.; Nilges, M.J.; Munck, E.; Yi Lu, Y. "Redesigning an Electron Transfer Protein into a Mononuclear Non-heme Iron Enzyme: Preparation and Study of Fe(II)-M121E Azurin", J. Am. Chem. Soc. 2014, 136, 12337-44.

298    Makris, T.M.;  Vu, V.V;  Meier,K.K.;  Komor,A.J.; Rivard, B.S.; Münck, E.; Que, Jr.,L.; Lipscomb, J.D. “An Unusual Peroxo Intermediate of the Arylamine Oxygenase of the Chloramphenicol Biosynthetic Pathway”, J. Am. Chem. Soc. 2015, 137, 1608-17.

299    Biswas,A.N.; Puri, M.;  Meier, K.K.; Oloo, W.N.;  Rohde, G.T.
 Bominaar, E.L.; Munck, E.; Que, Jr.,L. “Modeling TauD-J: A high-spin non-hemeoxoiron (iV) complex that is highly reactive toward C=C and strong C-H bonds” J. Am. Chem Soc. 2015,137, 2428-31.

300   Prakash, J.; Rohde, G. T.; Meier, K. K.; Jasniewski, A. J.; Van Heuvelen, K. M.; Münck, E.; Que, Jr., L. “Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺” J. Am. Chem. Soc. 2015,137, 3478-81.

301    Serrano-Plana, J.; Oloo, W. N.; Acosta-Rueda, L. M.; Meier, K. K.; Verdejo, B.; Garcia-Espana, E.; Basallote, M. G.; Münck, E.; Que, Jr., L.; Company, A.; Costas, M. “Trapping a Highly Reactive Non-heme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention.”  J. Am. Chem. Soc. 2015, 137, 15833-42.

302    Meier, K. K.; Rogers, M.; Kovaleva, E. G.; Bominaar, E.; Lipscomb, J. D.; Münck, E. “ A long-lived FeIII(hydroperoxo) intermediate in the active H200C variant of homoprotocatechuate 2,3-dioxygenase: Characterization by Mössbauer, Electron Paramagnetic Resonance, and Density Functional Theory methods.” Inorg. Chem. 2015, 54, 10269-80

303    Prakash, J.; Rohde,G.T.;  Meier, K.K.;  Münck, E.; and  Que, L. Jr.  "Upside Down! Crystallographic and Spectroscopic Characterization of an [FeIV(Osyn)(tetramethylcyclam)]2+ Complex. Inorg. Chem. 2015, 54, 11055-7

304    England, J; Prakash, J.; Cranswick, M.A.; Mandal, D.; Guo, Y.; Münck, E.; Shaik, S.; Que, L. Jr. “Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me2EBC” Inorg. Chem. 2015, 54, 7828-39.

305    Meier, K.K.; Rogers, M.S.; Kovaleva, E.G.; Lipscomb, J.D.; Münck E.; Bominaar, E.L. “Enzyme Substrate Complex of the H200C Variant of     Homoprotocatechuate 2,3-Dioxygenase: Mössbauer and Computational Studies”. Inorg. Chem. 2016, 55, 5862-70.

306    Stout, H.; Kleespies, S. D.; Chiang, C-W.; Lee, W-Z.; Que, L.; Munck, E.; Bominaar, E.L. “Spectroscopic and Theoretical study of spin-dependent electron transfer in an FeIII superoxo complex”, Inorg. Chem. 2016, 55, 5216-26.

307    Bigelow, J. O.; England J.; Klein, J.E.M.N; Farquhar, E.R.; Frisch J.A. R.; Martinho, M.; Mandal, D. ; Munck, E.; Shaik, S. ;Que, L.   Oxoiron(IV)Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effects of Tethering the Carboxylate on Reactivity” Inorg. Chem. 2017, 56, 3297-3301.

308    Fan, R. ; Serrano-Plana, J.; Oloo, W.N. Draksharapu, A.; Company A.; Borrell, M., Lloret-Fillol, J.; Guo, Y.; Bominar, E.B.; Que, L.; Costas, M.; Münck, E. “Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV=O Intermediate” J. Am. Chem. Soc., submitted





updated 01/2014