Publications
(separated by decade)
Selected
Publications
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1. Rohde, J.-U.; In, J.-H.; Lim, M.
H.; Brennessel, W. W.; Bukowski, M. R.; Stubna, A.; Münck, E.; Nam, W.; Que
Jr., L.“Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)=O
Complex” Science 2003, 299, 1037-1039.
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2. Andres, H.; Bominaar,
E.; Smith, J. M.; Eckert, N. E.; Holland, P.; Münck, E. “Planar
Three-Coordinated High-Spin FeII Complexes with Large Orbital
Angular Momentum: Mössbauer, EPR and Electronic Structure Studies” J.
Am. Chem. Soc. 2002, 124, 3012-3025.
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3. Vrajmasu, V. V.; Münck,
E.; Bominaar, E. L. “Theoretical Analysis of the Jahn-Teller Distortions in
Tetrathiolato Iron(II) Complexes” Inorg. Chem. 2004,
43, 4862-4866.
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4. Sutton, V. R.; Stubna,
A.; Patschkowski, T.; Münck, E.; Beinert, H.; Kiley, P. J. “Superoxide
Destroys the [2Fe-2S]2+ Cluster of FNR from Escherichia coli”
Biochemistry 2004, 43, 791- 798.
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5. Stubna, A; Jo, D.-H.;
Costas, M.; Brenessel, M.; Andres, H.; Bominaar, E. L.; Münck, E.; Que, L.,
Jr. “A Structural and Mössbauer Study of Complexes with Fe2(µ-O(H))2
Cores: Stepwise Oxidation from FeII(µ-OH)2FeII
through FeII(µ-OH)2FeIII to FeIII((µ-O)(µ-OH)FeIII”
Inorg. Chem. 2004, 43, 3067-3079
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6. Tiago de Oliveira, F.;
Bominaar, E. L.; Hirst, J.; Fee, J. A.; Münck, E. “Antisymmetric Exchange
in [2Fe-2S]1+ Clusters: EPR of the Rieske Protein from Thermus
thermophilus at pH 14” J. Am. Chem. Soc. 2004,
126, 5338-5339.
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7. Ghosh, A.; Tiago deOliveria,
F.; Yano, T.; Beach, E. S.; Nishioka, T.; Kinoshita, I.; Wallen, S. L.;
Münck, E.; Ryabov, A. D.; Horwitz, A. D.; Collins, T. J. “Direct
Interaction of Ferric Iron with Dioxygen to Produce Reactive µ-Oxo Iron(IV)
Dimers” J. Am. Chem. Soc. 2005, 127, 2505-2513.
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8. Jensen, M. P; Costas, M.; Ho,
R. Y. N.; Kaizer, J.; Mairata i Payeras, A.; Münck, E.; Que Jr., L.; Rohde,
J.; Stubna, A. “High-Valent Nonheme Iron: Two Distinct Iron(IV)
Intermediates Derived from Fe(ß-BPMCN)(OTf)2” J. Am. Chem.
Soc. 2005, 127, 10512-10525.
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9. Stoian, S.; Yu, Y.;Smith, J.
M.; Holland, P. A.; Bominaar, E. L.; Münck, E. “Mössbauer, EPR, and
Crystallographic Characterization of a High-spin FeI
Diketiminate Complex with Orbital Degeneracy” Inorg. Chem.
2005, 44, 4915-4922.
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10. Bukowski, M. R.; Koehntop, K. D.;
Stubna, A.; Bominaar, E. L.; Halfen, J. A.; Münck, E.; Nam,W.; Que
Jr., L. “A Non-Heme Fe(IV) Complex with a Thiolate Ligand Relevant to P450”
Science 2005, 310, 1000-1002.
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11. Pestovsky, O.; Stoian, S.;
Bominaar, E. L.; Shan, X.; Münck, E.; Que, L.; Bakac, A. “Aqueous Fe(IV)=O:
Spectroscopic Identification and Oxo-Group Exchange” Angew. Chem. 2005,
44, 2-6.
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12. Tiago
de Oliveira, F.; Chanda, A.; Banerjee, D.; Shan, X.; Mondal, S.; Que, L.,
Jr.; Bominaar, E. L.; Münck, E.; Collins, T. J. "Chemical and
Spectroscopic Evidence for an Fe(V)-Oxo Complex" Science 2007,
315(5813), 835-838.
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13.
Hudder, B. N.; Garber-Morales, J.; Stubna, A.; Münck, E.; Hendrich, M. P.;
Lindahl, P. A. "Electron Paramagnetic Resonance and Mössbauer
Spectroscopy of Intact Mitochondria from Respiring Saccaromyces
cerevisiae" J. Biol. Inorg. Chem. 2007,
12, 1029-1053.
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14.
Xue, G.; Wang, D.; De Hont, R.; Fiedler, A.; Shan, X.; Münck, E.; Que, L.,
Jr. "A Synthetic Precedent for the [FeIV2(µ-O)2]
Diamond Core Proposed for Methane Monooxygenase Intermediate Q"
Proc. Natl. Acad. Sci. USA 2007,
104, 20713-18.
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15.
Martinho, M.; Choi, D. W.; DiSpirito, A. A.; Antholine, W. E.; Semrau, J.
D.; Münck, E. "Mössbauer Studies of the Membrane-Associated Methane
Monooxygenase from Methylococcus capsulatus Bath: Evidence for a
Diiron Center" J. Am. Chem. Soc. 2007, 129,
15783-5.
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16. Xue, G.,
Fiedler, A. T., Martinho, M., Münck, M., Que, L.Jr. “Insights into the
P-to-Q Conversion in the Catalytic Cycle of Methane Monooxygenase from a
Synthetic Model System” Proc. of the Natl. Acad. Sci. USA 2008,
105, 20615-20.
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17.
Chakrabarti, M.; Deng, L.; Holm, R.H.; Munck, E.; Bominaar, E. L.
“Mossbauer, Electron Paramagnetic Resonance, and Theoretical Studies of a
Carbene-Based All Ferrous FeS Cluster: Electronic Origin and Structural
Identification of the Unique Spectroscopic Site” Inorg. Chem. 2009,
48, 2735-47.(Cover page Inorg. Chem.
Apr. 6, 2009)
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18.
Martinho, M., Xue, Genqiang, Bominaar, E., Münck, E. Que,
L.Jr. “Mössbauer and DFT Study of the Ferromagnetically Coupled Diiron(IV)
Precursor to a Complex with an FeIV2O2 Diamond Core" J. Am. Chem.
Soc. 2009, 131, 5823-30.(JACS
Select #9 Article)
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19.
England J, Martinho M, Farquhar ER, Frisch JR, Bominaar
EL, Münck E, Que L Jr. “A synthetic high-spin Fe(IV) Complex: Generation,
Spectroscopic Characterization and Reactivity” Angew. Chem. Int. Ed.
2009, 48, 3622-3626.
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20. Vu,
V.V.; Emerson, J. P. ; Martinho, M. ; Kim, Y.S. ; Münck, E. ; Park, M.H. ;
Que Jr., L. “Reduced Diiron Site in Human Deoxyhypusin Hydroxylase can Bind
Dioxygen in Form of Diferric Peroxo Cluster”, Proc. Natl. Acad. Sci.
USA 2009, 106, 14814-9.
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21.
Xue, G.; De Hont, R.; Münck, E. ; Que, L., Jr. “
Million-fold Activation of the [Fe2(u-O)2] diamond core for C-H Bond
Cleavage” Nature Chem. 2010, 2, 400-405.
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22. Mukherjee,
A.; Cranswick, M.; Chakrabarti, M.; Paine, T.; Fujisawa, K.; Münck, E.;
Que, L. "Oxygen Activation at Mononuclear Nonheme Iron Centers: A
Superoxo Perspective" Inorg. Chem. 2010, 49,
3618-28.
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23.
Stoian, S.; Paraschiv, C.; Kyritsakas, N.; Lloret, F.;
Munck, E.; Bominaar, E.; Andruh, M. "Mössbauer, EPR, and magnetic
susceptibility studies on members of a new family of cyano-bridged 3d-4f
complexes. Demonstration of anisotropic exchange in a Fe-Gd complex" Inorg.
Chem. 2010, 49, 3387-3401.
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24. De
Hont, R. F.; Xue, G.; Hendrich, M. P. ; Que, L. ; Bominaar, E. L. ; Münck,
E. Mössbauer, EPR and DFT Studies of two Synthetic u-oxo bridged FeIVFeIII
S = ½ Complexes containing a high-spin FeIV=O site: 57Fe hyperfine
interactions and Exchange couplings” Inorg. Chem. 2010,
49, 8310-22.
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25.
England, J.; Guo, Y.; Farquhar, E.R.; Young, V. J.;
Munck, E.; Que, L. “The Crystal Structure of a High-Spin OxoIron(IV)
Complex and Characterization of Its Self-Decay Pathway” J. Am. Chem.
Soc. 2010, 132, 8635-44.
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26.
Holmes-Hampton, G.; Miao, R.; Garber-Morales, J.; Guo,
Y.; Münck, E.; Lindahl, P. "A Nonheme High-Spin Ferrous Pool in
Mitochondria Isolated from Fermenting Saccharomyces cerevisiae" Biochemistry
2010, 4, 4227-34.
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27.
Garber-Morales, J. Holmes-Hampton, G. P.; Miao, R.; Guo,
Y.; Münck, E.; Lindahl. P. A. “Characterization of Iron in Mitochondria
Isolated from Respiring and Fermenting Yeast” Biochemistry 2010,
49, 5436-44.
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28.
Makris, T. A. ; Chakrabarti, M.; Münck, E.; Lipscomb, J.
D. “A family of diiron monooxygenases catalyzing amino acid beta
hydroxylation in antibiotic biosynthesis” Proc. Natl. Acad. Sci. USA
2010,107, 15391-96.
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29.
Mbughuni, M.; Chakrabarti , M.; Title: Hayden , J.;
Bominaar, E. ; Hendrich, M, Münck, E.; Lipscomb, J. "Trapping and
spectroscopic characterization of an FeIII -superoxo intermediate from a
non-heme mononuclear iron-containing enzyme", Proc. Natl. Acad.
Sci. USA 2010, 107, 16788-93.
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30.
McDonald, A.; Bukowski, M.; Farquhar, E.; Jackson, T.;
Koehntop, K. ; Seo, Mi S.; De Hont, R.; Stubna, A.; Halfen, J.; Münck, E.;
Nam, W.; Que, L. "Sulfur versus Iron Oxidation in an Iron-Thiolate
Model Complex" J. Am. Chem. Soc. 2010,
17118-29.
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31. Bruijnincx
PC, Buurmans IL, Huang Y, Juha´sz G, Viciano-Chumillas M, Quesada M,
Reedijk J, Lutz M, Spek AL, Münck E, Bominaar EL, Klein Gebbink RJ
"Mono- and Dinuclear Iron Complexes of
Bis(1-methylimidazol-2-yl)ketone (bik): Structure, Magnetic Properties, and
Catalytic Oxidation Studies." Inorg. Chem. 2011, 19, 9243-55.
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32.
England, J.; Guo, Y.; Van Heuvelen, K. M. Cranswick,
M.A., Rohde, G. T.; Bominaal E. L.; Münck, E. Que, L. Jr "A more
reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a
cis-labile site." J. Am. Chem. Soc. 2011, 133, 11880-83.
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33.
Mbughuni, M.; Chakrabarti, M.; Hayden, J.A.; Meier, K. K.
, Dalluge, J.J.; Hendrich, M.P.; Münck, E.; Lipscomb, J.D.
"Oxy-Intermediates of Homoprotocatechate 2,3 Dioxygenase: Facile Electron
Transfer between Substrates" Biochemistry, 2011, 50,
10262-74.
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34. Van
Heuvelen, K. M.; Fiedler, A. T.; Shan, X.; De Hont, R. F.; Meier, K. K.; Bominaar,
E. L.; Münck, E.; Que, Jr., L.
"An [O=FeV=NR]+ Center Formed by One-Electron
Oxidation of an Oxoiron(IV) Complex" Proc. Natl. Acad. Sci. 2012,
109, 11933-38
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