As by July 2006, the
complete publication list has 167 entries. I am particularly proud of the
following works
Key
Reviews
A.
D. Ryabov "Cyclopalladated complexes in organic synthesis", Synthesis,
1985 (3), 233-252.
A.
D. Ryabov "Mechanisms of intramolecular activation of C-H bonds in
transition metal complexes", Chem. Rev., 1990, 90 (2),
403-424.
A.
D. Ryabov "The biochemical
reactions of organometallics with enzymes and proteins (Review)", Angew.
Chem., Int. Ed. English, 1991, 30 (8), 931-941.
A.
D. Ryabov "Synthetic and mechanistic aspects of exchange of
cyclometallated ligands in palladium(II) and platinum(II) complexes", in
"Perspectives in Coordination Chemistry", A. F. Williams, C.
Floriani, A. E. Merbach, eds., Verlag Helvetica Chimica Acta, Basel, VCH
Weinheim, NY, 1992, pp. 271-292.
A.
D. Ryabov, “Transition metal chemistry of glucose oxidase, horseradish
peroxidase, and related enzymes”, Adv. Inorg. Chem., 2004, 55,
201-270.
J.
Castillo, S. Gáspár, S. Leth, M. Niculescu, A. Mortari, I. Bontidean, V.
Soukharev, S. A. Dorneanu, A. D. Ryabov, E. Csöregi “Biosensors for life
quality. Design, development and applications”, Sensors and Actuators B:
Chemical, 2004, 102(2), 179-194.
Textbook
A.
D. Ryabov “A Concise Lecture Course in Modern Organic Chemistry”, Russian
Academy for National Economy Press, Moscow, 1995, Parts I and II.
Selected
Regular Papers
Cyclometalation by Platinum and Palladium
A.
D. Ryabov, A. K. Yatsimirsky "Reaction of ortho-palladated
dimethylbenzylamine with styrene: unexpected salt effect", Tetrahedron
Lett., 1980, 21 (28), 2757-2760.
A.
D. Ryabov, V. A. Polyakov, A. K. Yatsimirsky "Reaction paths in the
cyclopalladated NN-dialkylbenzylamine-substitut
A.
D. Ryabov, I. K. Sakodinskaya, A. K. Yatsimirsky "Kinetics and mechanism
of vinylation of ortho-palladated NN-dialkylbenzylamines by para-substituted
styrenes", J. Chem. Soc., Perkin Trans. 2, 1983 (10),
1511-1518.
A.
D. Ryabov, V. A. Polyakov, A. K. Yatsimirsky "Some complexes of
palladaium(II) C-phenylglycine and its derivatives. Cyclopalladation of
N,N-dimethyl-C-phenylglycine ethyl ester", Inorg. Chim. Acta, 1984,
91 (1), 59-65.
A.
D. Ryabov, A. K. Yatsimirsky "Exchange of cyclopalladated ligands in
chloro-bridged palladium(II) complexes", Inorg. Chem., 1984,
23 (6), 789-790.
A.
D. Ryabov, I. K. Sakodinskaya, A. K. Yatsimirsky "Kinetics and mechanism
of ortho-palladation of ring substituted NN-dimethylbenzylamines", J.
Chem. Soc., Dalton Trans., 1985 (12), 2629-2638.
A.
D. Ryabov "Thermodynamics, kinetics, and mechanism of exchange of
cyclopalladated ligands", Inorg. Chem., 1987, 26 (8),
1252-1260.
A.
D. Ryabov, A. V. Eliseev, E. S. Sergeyenko, A. V. Usatov, L. I. Zakharkin, V.
N. Kalinin "Cyclopalladated o-carboranes. Palladium transfer from
cyclopalladated N,N-dimethylbenzylamines, 1-C-diphenylphosphino-o
A.
D. Ryabov, G. M. Kazankov, A. K. Yatsimirsky, L. G. Kuz'mina, O. Yu. Burtseva,
N. V. Dvortsova, V. A. Polyakov "Synthesis by ligand exchange, structural
characterization, and aqueous chemistry of ortho-palladated oximes", Inorg.
Chem., 1992, 31 (14), 3083-3090.
A.
D. Ryabov, R. van Eldik, G. Le Borgne, M. Pfeffer "Insertion of alkynes
into the Pd-C Bond of palladacycles. Mechanistic information from high pressure
kinetic and X-ray structural data", Organometallics, 1993, 12
(4), 1386-1393.
A.
D. Ryabov, R. van Eldik "An Easy Route to Homo- and Heteroleptic
Biscycloplatinated Complexes without Recourse to Organolithium Compounds",
Angew. Chem., Int. Ed. Engl., 1994, 33 (7), 783-784.
E.
V. Krooglyak, G. M. Kazankov, S. A. Kurzeev, V. A. Polyakov, A. N. Semenov, A.
D. Ryabov "Targeting of Pallada- and Platinacycles to the
N-((tert-Butyloxy)carbonyl)-L
A.
D. Ryabov, G. M. Kazankov, I. M. Panyashkina, O. V. Grozovsky, O. G. Dyachenko,
V. A. Polyakov, L. G. Kuz'mina “Cycloplatination of aryl and ferrocenyl oximes
by cis-[PtCl2(OSMe2)2] affording
expected platinum(II) and unexpected platinum(IV) Products.”, J. Chem. Soc.,
Dalton Trans., 1997 (22), 4385-4391.
A.
D. Ryabov, I. M. Panyashkina, V. A. Polyakov, J. A. K. Howard, L. G. Kuz'mina,
M. S. Datt, C. Sacht, "An Access to Planar Chirality through
Cycloplatination of Dimethylaminomethylferrocene by cis-[PtCl2(SOMeAr)2]
(Ar = Phenyl and p-Tolyl)”, Organometallics, 1998, 17
(16), 3615-3618.
R.
A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beek, R. van
Eldik, G. van Koten, “Models for the Initial Stages of Oxidative Addition.
Synthesis, Characterization and Mechanistic Investigation hη1-I2
Organometallic “Pincer” Complexes of the Platinum Group Metals. The X-Ray
Crystal Structures of [PtI(C6H3{CH2NMe2}2-2,6)(hη1-I2)],
exo-meso-[Pt(hη1-I3)(hη1-I2)(C6H3{CH2NMe2}2-2,6)]
and [PdI(C6H3{CH2NMe2}2-2,6)]·(I2)2”
J. Am. Chem. Soc. 1999, 121 (11), 2488-2497.
L.
Alexandrova, O. G. D'yachenko, G. M. Kazankov, V. A. Polyakov, P. V. Samuleev,
E. Sansores, A. D. Ryabov “Mechanism of biologically relevant deoxygenation of
dimethyl sulfoxide coupled with Pt(II) to Pt(IV) oxidation of orthoplatinated
oximes. Synthetic, kinetic, electrochemical, X-ray structural, and
density functional study”, J. Am. Chem. Soc., 2000, 122 (14),
5189-5200.
G.
M. Kazankov, V. S. Sergeeva, E. N. Efremenko, L. Alexandrova, S. D.
Varfolomeev, A. D. Ryabov, “Highly Efficient Degradation of Thiophosphate
Pesticides Catalyzed by Platinum and Palladium Aryl Oxime Metallacycles”, Angew.
Chem., Int. Ed. Engl., 2000, 39 (17), 3117-3119.
A.
D. Ryabov, I. M. Panyashkina, V. A. Polyakov, A. Fischer, “Access to Central
Carbon Chirality Through Cycloplatination of 1-(2-pyridinylthio)propanone by cis-[PtCl2(S-SOMe(p-tolyl)].
A Crystal Structure of (SsSc)-[Pt{py{SCHC(O)Me-2}Cl(SOMe(p-tolyl))]”,
Organometallics, 2002, 21 (8), 1633-1636.
A.
D. Ryabov, S. Otto, P. V. Samuleev, V. A. Polyakov, L. Alexandrova, G. M.
Kazankov, S. Shova, M. Revenco, J. Lipkowski, and M. H. Johansson, „Structural
and Mechanistic Look at the Orthoplatination of Aryl Oximes by
Dichlorobis(sulfoxide or sulfide)platinum(II) Complexes”, Inorg. Chem. 2002,
41 (16), 4286-4294.
S.
Otto, A. Chanda, P. V. Samuleev, A. D. Ryabov “DFT-Verified Crystallographic
Mechanism of Cycloplatination” Eur. J. Inorg. Chem. 2006 (13),
2561-2565.
Organometallic Biochemistry
A.
D. Ryabov, E. M. Tyapochkin, S. D. Varfolomeev, A. A. Karyakin "Ferrocenes
inside the cyclodextrin cavities do not mediate the electron transport between
glucose oxidase and an electrode", Bioelectrochemistry Bioenergetics,
1990, 24 (2), 257-262.
A.
D. Ryabov, A. M. Trushkin, L. I. Baksheeva, R. K. Gorbatova, I. V. Kubrakova,
V. V. Mozhaev, B. B. Gnedenko, A. V. Levashov "Chemical attachment of
organometallics to proteins in reverse micelles", Angew. Chem., Int.
Ed. English, 1992, 31 (6), 789-790.
B.
B. Gnedenko, A. D. Ryabov "Biodegradation of Soluble Redox Polymers. 1.
(0.017Ferrocene)Amylose", Anal. Chem., 1994, 66 (14),
2240-2244.
A.
D. Ryabov, A. Amon, R. K. Gorbatova, E. S. Ryabova, B. B. Gnedenko,
"Mechanism of "Jumping Off" Ferricenium in the Glucose Oxidase-D-Glucose-Ferrocene
Micellar Electrochemical Systems", J. Phys. Chem., 1995, 99
(38), 14072-14077.
A.
D. Ryabov, V. N. Goral “Steady-State Kinetics, Micellar Effects, and The
Mechanism of Peroxidase-Catalyzed Oxidation of n-Alkylferrocenes by Hydrogen
Peroxide", J. Biol. Inorg. Chem., 1997, 2 (2),
182-190.
A.
D. Ryabov, Y. N. Firsova, V. N. Goral, E. S. Ryabova, A. N. Shevelkova, L. L.
Troitskaya, T. V. Demeschik, V. I. Sokolov, "Enantioselectivity in
Enzyme-Catalyzed Electron Transfer To and From Planar Chiral Organometallic
Compounds ". Chem. Eur. J. 1998, 4 (5), 806-813.
A.
D. Ryabov, V. S. Kurova, V. N. Goral, M. D. Reshetova, J. Razumiene, R. Simkus,
and V. Laurinavičèius “p-Ferrocenylaniline and p-Ferrocenylphenol:
Promising Materials for Analytical Biochemistry and Bioelectrochemistry”, Chem.
Mater., 1999, 11 (3), 600-604.
A.
D. Ryabov, V. N. Goral, L. Gorton, and E. Csöregi “Electrochemically and
Catalytically Active Reconstituted Horseradish Peroxidase with
Ferrocene-Modified Hemin and Artificial Binding Site”, Chem. Eur. J., 1999,
5 (3), 961-967.
J.
Razumienė, R. Meškys, V. Gurevičienė, V. Laurinavičius, M. D. Reshetova, A. D.
Ryabov ”4-Ferrocenylphenol as an electron transfer mediator in PQQ-dependent
alcohol and glucose dehydrogenase-catalyzed reactions”, Electrochem. Commun.
2000, 2 (5), 307-311.
Enzymology
A.
N. Shevelkova, Yu. I. Sal’nikov, N. L. Kuz'mina, A. D. Ryabov, “Thermodynamic”
Mechanism of Catalysis by Haloperoxidases”, FEBS Lett., 1996, 383
(3), 259-263.
Cyclometalation by Ruthenium
W.
Ferstl, I. K. Sakodinskaya, N. Beydoun-Sutter, G. Le Borgne, M. Pfeffer, A. D.
Ryabov, “Mechanism of Alkyne Insertion into the Ru-C Bonds of Orthoruthenated
Compounds Featuring Similarity of the Ru(II) and Pd(II) Reactions”, Organometallics,
1997, 16 (3), 411-418.
Biochemistry of Ruthenium and Osmium Metalacycles
E.
S. Ryabova, V. N. Goral, E. Csöregi, B. Mattiasson, and A. D. Ryabov,
“Coordinative Approach to Mediated Electron Transfer: Ruthenium Complexed to
Native Glucose Oxidase”, Angew. Chem. Int. Ed. Engl. 1999, 38(6)
804-807; Angew. Chem. 1999, 111 (6), 847-850.
A.
D. Ryabov, V. S. Sukharev, L. Alexandrova, R Le Lagadec, M. Pfeffer, “New
Synthesis and New Bio-Application of Cyclometalated Ruthenium(II) Complexes for
Fast Mediated Electron Transfer with Peroxidase and Glucose Oxidase”, Inorg.
Chem., 2001, 40 (25),
6529-6532.
I.
S. Alpeeva, V. S. Soukharev, L. Alexandrova, N. V. Shilova,N. V. Bovin, E.
Csöregi, A. D. Ryabov, I. Yu. Sakharov, “Cyclometalated Ruthenium(II) Complexes
As Efficient Redox Mediators in Peroxidase Catalysis”, J. Biol. Inorg. Chem.,
2003, 8 (6), 683-688.
A.
D. Ryabov, V. S. Soukharev, L. Alexandrova, R. Le Lagadec, M. Pfeffer,
“Low-Potential Cyclometalated Osmium(II) Mediators of Glucose Oxidase”, Inorg.
Chem., 2003, 42 (21), 6598-6600.
A.
D. Ryabov, V. S. Kurova, E. V. Ivanova, R. Le Lagadec, L. Alexandrova
"Redox Mediation and Photomechanical Oscillations Involving
Photo-Sensitive Cyclometalated Ru(II) Complexes, Glucose Oxidase and
Peroxidase", Anal. Chem. 2005, 77 (4), 1132-1139.
A.
D. Ryabov, R. Le Lagadec, H. Estevez, R. A. Toscano, S. Hernandez, L.
Alexandrova, V. S. Kurova, A. Fischer, C. Sirlin, M. Pfeffer “Synthesis,
Characterization, and Electrochemistry of Bio-relevant Photosensitive
Low-Potential Orthometalated Ruthenium Complexes”, Inorg. Chem. 2005,
44 (5), 1626-1634.
R.
Le Lagadec, L. Alexandrova, H. Estevez, M. Pfeffer, V. Laurinavičius, J.
Razumiene, A. D. Ryabov “Bis-Ruthena(III)cycles [Ru(C∩N)2(N∩N)]PF6
as Low Potential Mediators for PQQ Alcohol Dehydrogenase (C∩N =
2-phenylpyridinato, N∩N = bpy or phen.” Eur. J. Inorg. Chem. 2006
(14), 2735-2738.
Iron(III) TAMLs
A.
Ghosh, A. D. Ryabov, S. M. Mayer, D. C. Horner, D. E. Prasuhn, Jr., S. Sen
Gupta, L. Vuocolo, C. Culver, M. P. Hendrich, C. E. F. Rickard, R. E. Norman,
C. P. Horwitz, T. J. Collins, “Understanding the Mechanism of H+-Induced
Demetalation as a Design Strategy for Robust Iron(III)-Peroxide-Activating
Catalysts”, J. Am. Chem. Soc. 2003, 125 (41),
12378-12379.
A.
Ghosh, F. Tiago deOliveria, T. Yano, T. Nishioka, E. S. Beach, I. Kinoshita, E.
Münck, A. D. Ryabov, C. P. Horwitz, T. J. Collins “Catalytically active m-oxodiiron(IV)
oxidants from iron(III) and dioxygen”, J. Am. Chem. Soc. 2005, 127
(8), 2505-2513.