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About the Matyjaszewski Group
Center for Macromolecular Engineering
CRP Consortium
ATRP Consortium
(1996–2000)
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Wade Braunecker
Research Interests
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Transition metal catalyzed polymerization |
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Interplay of polymerization mechanisms |
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Copolymerization of polar, functional monomers with simple alpha-olefins |
National and International Presentations
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234th ACS National Meeting, August 19-23, 2007, Boston, MA |
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Gordon Research Conference on Polymers (East), June 17-22, 2007, Mount Holyoke College, MA |
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38th ACS Middle Atlantic Regional Meeting, June 4-7, 2006, Hershey, PA |
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230th ACS National Meeting, August 28 - September 1, 2005, Washington, D.C. |
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5th International School on Molecular Catalysis, August 12-16, 2005, Rosnówko, Poland |
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16th International Symposium on Olefin Metathesis, August 7-12, 2005, Poznañ, Poland |
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228th ACS National Meeting, August 22-26, 2004, Philadelphia, PA |
Peer Reviewed Journal Publications
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Braunecker, W. A., Brown, W. C., Morelli, B. C., Tang, W., Poli, P., Matyjaszewski, K. "On the Origin of Activity in Cu, Ru, and Os Mediated Radical Polymerization" Macromolecules, accepted. |
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Matyjaszewski, K., Tsarevsky, N. V., Braunecker, W. A., et. al. "Atom Transfer Radical Polymerization in the Presence of Cu(0) 'Activators Regenerated by Electron Transfer or Single Electron Transfer Living Radical Polymerization'", Macromolecules, accepted. |
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Tsarevsky, N. V., Braunecker, W. A., Matyjaszewski, K. "Electron Transfer Reactions Relevant to Atom Transfer Radical Polymerization", J. Organomet. Chem., 2007, 692, 3212-3222. |
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Tsarevsky, N. V., Braunecker, W. A., Vacca, A., Gans, P., Matyjaszewski, K. "Competitive Equilibria in Atom Transfer Radical Polymerization", Macromol. Symp., 2007, 248, 60-70. |
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Braunecker, W. A., Matyjaszewski, K. “Controlled/Living Radical Polymerization: Features, Developments, and Perspectives”, Prog. Polym. Sci., 2007, 32, 93-146 |
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Tang, H., Arulsamy, N., Radosz, M., Shen, Y., Tsarevsky, N. V., Braunecker, W. A., Tang, W., Matyjaszewski, K. “Highly Active Copper-based Catalyst for Atom Transfer Radical Polymerization”, J. Am. Chem. Soc., 2006, 128, 16277-16285. |
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Matyjaszewski, K., Jakubowski, W., Min, K., Tang, W., Huang, J., Braunecker, W. A., and Tsarevsky, N. V., “Diminishing Catalyst Concentration in Atom Transfer Radical Polymerization with Reducing Agents”, Proc. Nat. Acad. Sci. (U.S.A.), 2006, 103, 15309-15314. |
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Tsarevsky, N. V., Braunecker, W. A., Brooks, S. J., and Matyjaszewski, K. “Rational Selection of Catalysts for the Copper-Mediated Atom Transfer Radical Polymerization of Basic Monomers in Protic Media: ATRP of 4-Vinylpyridine”, Macromolecules, 2006, 39, 6817-6824. |
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Tsarevsky, N. V., Braunecker, W. A., Tang, W., Brooks, S. J., Matyjaszewski, K., Weisman, G. R., and Wong, E. H., “Copper-Based ATRP Catalysts of Very High Activity Derived from Dimethyl Cross-Bridged Cyclam”, J. Molecular Catalysis A: Chem., 2006, 257, 132-140. |
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Braunecker, W. A., Matyjaszewski, K., “Recent Mechanistic Developments in Atom Transfer Radical Polymerization”, J. Molecular Catalysis A: Chem., 2006, 254, 155-164. |
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Braunecker, W. A., Itami, Y., Matyjaszewski, K., “Osmium-Mediated Radical Polymerization”, Macromolecules 2005, 38, 9402-9404. |
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Braunecker, W. A., Tsarevsky, N. V., Pintauer, T., Gil, R. R., Matyjaszewski, K., “Quantifying Vinyl Monomer Coordination to Cu(I) in Solution and the Effect of Coordination on Monomer Reactivity in Radical Copolymerization”, Macromolecules 2005, 38, 4081-4088. |
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Braunecker, W. A., Pintauer, T., Tsarevsky, N. V., Kickelbick, G., Matyjaszewski, K., “Towards Understanding Monomer Coordination in ATRP: Synthesis of [CuI(PMDETA)(pi-M)][BPh4] (M = Methyl Acrylate, Styrene, 1-Octene, and Methyl Methacrylate) and Structural Studies by FT-IR and 1H NMR Spectroscopy and X-Ray Crystallography”, J. Organomet. Chem. 2005, 690, 916-924. |
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Pintauer, T., Braunecker, W., Collange, E., Poli, R., Matyjaszewski, K., “Determination of Rate Constants for the Activation Step in Atrom Transfer Radical Polymerization Using the Stopped-Flow Technique”, Macromolecules 2004, 37, 2679-2682. |
Book Chapters
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Matyjaszewski, K., Braunecker, W. A. "(Controlled/Living) Radical Polymerization", in Macromolecular Engineering. Precise Synthesis, Materials Properties, Applications, Vol. 1, p 161-215, Matyjaszewski, K. Gnanou, Y., Leibler, L., Eds., (2007). ISBN: 978-3-527-31446-1 |
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Braunecker, W. A., Matyjaszewski, K. “Fine Tuning Radical Polymerization Processes to Improve the Macroscopic Properties of Materials”, in Education in Advanced Chemistry: Organic and Polymer Synthesis and Catalysis , Vol. 10, p 63-75, Marciniec, B., Ed., (2006). ISBN: 83-7177-440-0. |
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