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Institute for Green Science, Carnegie Mellon return to homepage Carnegie Mellon Homepage

Publications

The Foundations of TAML Technology

  • Polshin, V.; Popescu, D.-L.; Fischer, A.; Chanda, A.; Horner, D. C.; Beach, E. S.; Henry, J.; Qian, Y.-L.; Horwitz, C. P.; Lente, G.; Fabian, I.; Muenck, E.; Bominaar, E. L.; Ryabov, A. D.; Collins, T. J., Attaining Control by Design over the Hydrolytic Stability of Fe-TAML Oxidation Catalysts. J. Am. Chem. Soc. 2008, 130, (13), 4497-4506.
  • Popescu, D.-L., Chanda, A., Stadler, M., Tiago de Oliveira, F., Ryabov, A. D., Münck, E., Bominaar, E. L., Collins, T. J., High-Valent First-Row Transition-Metal Complexes of Tetraamido (4N) and Diamidodialkoxido or Diamidophenolato (2N/2O) Ligands: Synthesis, Structure, and Magnetochemistry, Coord. Chem. Rev., 2007, 0000.
  • Tiago de Oliveira, F.; Chanda, A.; Banerjee, D.; Shan, X.; Mondal, S.; Que, L., Jr.; Bominaar, E. L.; Muenck, E.; Collins, T. J., Chemical and Spectroscopic Evidence for an FeV-Oxo Complex. Science (Washington, DC, U. S.) 2007, 315, (5813), 835-838.
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  • Chanda, A.; Ryabov, A. D.; Mondal, S.; Alexandrova, L.; Ghosh, A.; Hangun-Balkir, Y.; Horwitz, C. P.; Collins, T. J., Activity-stability parameterization of homogeneous green oxidation catalysts. Chem.--Eur. J. 2006, 12, (36), 9336-9345.
  • Chanda, A.; Popescu, D.-L.; Tiago de Oliveira, F.; Bominaar, E. L.; Ryabov, A. D.; Muenck, E.; Collins, T. J., High-valent iron complexes with tetraamido macrocyclic ligands: Structures, Moessbauer spectroscopy, and DFT calculations. J. Inorg. Biochem. 2006, 100, (4), 606-619.
  • Ghosh, A.; Tiago de Oliveira, F.; Yano, T.; Nishioka, T.; Beach Evan, S.; Kinoshita, I.; Munck, E.; Ryabov Alexander, D.; Horwitz Colin, P.; Collins Terrence, J., Catalytically active μ-Oxodiiron(IV) oxidants from Iron(III) and dioxygen. J. Am. Chem. Soc. 2005, 127, (8), 2505-13.
    (abstract)
  • Ghosh, A.; Ryabov Alexander, D.; Mayer Sherry, M.; Horner David, C.; Prasuhn Duane, E., Jr.; Sen Gupta, S.; Vuocolo, L.; Culver, C.; Hendrich Michael, P.; Rickard Cliffton, E. F.; Norman Richard, E.; Horwitz Colin, P.; Collins Terrence, J., Understanding the mechanism of H(+)-induced demetalation as a design strategy for robust iron(III) peroxide-activating catalysts. J. Am. Chem. Soc. 2003, 125, (41), 12378-9.
  • Gordon-Wylie, S. W.; Blanton, W. B.; Claus, B. L.; Horwitz, C. P.; Collins, T. J.; Boskovic, C.; Christou, G., Syntheses of selected supramolecules. Toward magnetic building blocks: Synthesis of a planar Co(III)-cation radical-cobalt(III) complex of the binucleating ligand 1,2,4,5-tetrakisbenzene. Inorg. Synth. 2002, 33, 1-10.
  • Glatzel, P.; Bergmann, U.; Gu, W.; Wang, H.; Stepanov, S.; Mandimutsira, B. S.; Riordan, C.; Horwitz, C. P.; Collins, T.; Cramer, S. P., Electronic Structure of Ni Complexes by X-ray Resonance Raman Spectroscopy (Resonant Inelastic X-ray Scattering). J. Am. Chem. Soc. 2002, 124, (33), 9668-9669.
  • Collins, T. J., TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems. Acc. Chem. Res. 2002, 35, (9), 782-790.
  • Horwitz, C. P.; Gordon-Wylie, S. W.; Leychkis, Y.; Flynn, D. M.; Weintraub, S. T.; Clark, G. R.; Collins, T. J., Modifying the Chemistry of a Macrocyclic Cobalt Complex by Remote Site Manipulation. J. Phys. Chem. B 2001, 105, (37), 8821-8828.
  • Patterson, R. E.; Gordon-Wylie, S. W.; Woomer, C. G.; Norman, R. E.; Weintraub, S. T.; Horwitz, C. P.; Collins, T. J., Electron-Transfer Oxidation by Phase-Separating Reagents. Inorg. Chem. 1998, 37, (18), 4748-4750.
  • Miller, C. G.; Gordon-Wylie, S. W.; Horwitz, C. P.; Strazisar, S. A.; Peraino, D. K.; Clark, G. R.; Weintraub, S. T.; Collins, T. J., A Method for Driving O-Atom Transfer: Secondary Ion Binding to a Tetraamide Macrocyclic Ligand. J. Am. Chem. Soc. 1998, 120, (44), 11540-11541.
  • Horwitz, C. P.; Fooksman, D. R.; Vuocolo, L. D.; Gordon-Wylie, S. W.; Cox, N. J.; Collins, T. J., Ligand design approach for securing robust oxidation catalysts. J. Am. Chem. Soc. 1998, 120, (19), 4867-4868.
  • Bartos, M. J.; Gordon-Wylie, S. W.; Fox, B. G.; James Wright, L.; Weintraub, S. T.; Kauffmann, K. E.; Munck, E.; Kostka, K. L.; Uffelman, E. S.; Rickard, C. E. F.; Noon, K. R.; Collins, T. J., Designing ligands to achieve robust oxidation catalysts. Iron based systems. Coord. Chem. Rev. 1998, 174, 361-390.
  • Bartos, M. J.; Kidwell, C.; Kauffmann, K. E.; Gordon-Wylie, S. W.; Collins, T. J.; Clark, G. C.; Muenck, E.; Weintraub, S. T., A stable aquairon(III) complex with S = 1: structure and spectroscopic properties. Angew. Chem., Int. Ed. Engl. 1995, 34, (11), 1216-19.
  • Bartos, M.J.; Kidwell, C.; Kauffmann, K.E.; Gordon-Wylie, S.W.; Collins, T.J.; Clark, G.C.; Münck, E.; Weintraub, S.T., A Stable Oxidized Iron Water Complex, Angew. Chem. Int. Edn. Engl., 1995, 34, 1216–1219.
  • Kauffmann, K.E.; Bartos, M.J.; Kidwell, C.; Gordon-Wylie, S.W.; Collins, T.J.; Clark, G.R.; Weintraub, S.T.; Münck, E., Mössbauer Studies of a Novel Non-Heme Intermediate Spin Iron(III) Exchange-Coupled to a Ligand Radical, J. Inorg. Biochem., 1995, 59, 317.
  • Kostka, K. L.; Fox, B. G.; Hendrich, M. P.; Collins, T. J.; Rickard, C. E. F.; Wright, L. J.; Munck, E., High-valent transition metal chemistry. Moessbauer and EPR studies of high-spin (S = 2) iron(IV) and intermediate-spin (S = 3/2) iron(III) complexes with a macrocyclic tetraamido-N ligand. J. Am. Chem. Soc. 1993, 115, (15), 6746-57.
  • Collins, T. J.; Workman, J. M., Structure of tetraphenylphosphonium micro -{[h4-2,4-bis(2-hydroxy-2-methylpropanamido)-2,4-dimethyl-3-oxopentane]cobalt(III)}tetranitratocerium(III) dichloromethane. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1993, C49, (8), 1426-8.
  • Workman, J. M.; Powell, R. D.; Procyk, A. D.; Collins, T. J.; Bocian, D. F., Vibrational and electrochemical properties of a series of stable manganese(V)-oxo complexes. Inorg. Chem. 1992, 31, (9), 1548-50.
  • Collins, T. J.; Fox, B. G.; Hu, Z. G.; Kostka, K. L.; Munck, E.; Rickard, C. E. F.; Wright, L. J., High valent transition metal chemistry. Synthesis and characterization of an intermediate-spin iron(IV) complex of a strong pi-acid ligand. J. Am. Chem. Soc. 1992, 114, (22), 8724-5.
  • Collins, T. J.; Powell, R. D.; Slebodnick, C.; Uffelman, E. S., Stable highly oxidizing cobalt complexes of macrocyclic ligands. J. Am. Chem. Soc. 1991, 113, (22), 8419-25.
  • Collins, T. J.; Nichols, T. R.; Uffelman, E. S., A square-planar nickel(III) complex of an innocent ligand system. J. Am. Chem. Soc. 1991, 113, (12), 4708-9.
  • Collins, T. J.; Kostka, K. L.; Uffelman, E. S.; Weinberger, T. L., Design, synthesis, and structure of a macrocyclic tetraamide that stabilizes high-valent middle and later transition metals. Inorg. Chem. 1991, 30, (22), 4204-10.
  • Collins, T. J.; Slebodnick, C.; Uffelman, E. S., Chromium(V)-oxo complexes of macrocyclic tetraamido-N ligands tailored for highly oxidized middle transition metal complexes: a new oxygen-18-labeling reagent and a structure with four nonplanar amides. Inorg. Chem. 1990, 29, (18), 3433-6.
  • Collins, T. J.; Powell, R. D.; Slebodnick, C.; Uffelman, E. S., A water-stable manganese(V)-oxo complex: definitive assignment of a nMnv==O infrared vibration. J. Am. Chem. Soc. 1990, 112, (2), 899-901.
  • Collins, T. J.; Kostka, K. L.; Munck, E.; Uffelman, E. S., Stabilization of mononuclear five-coordinate iron(IV). J. Am. Chem. Soc. 1990, 112, (14), 5637-9.
  • Collins, T. J.; Workman, J. M., Nonplanar amido groups only through carbon-nitrogen bond twisting. Angew. Chem. 1989, 101, (7), 924-5.
  • Collins, T. J.; Uffelman, E. S., A nonplanar amide group in ligands: the first macrocyclic square planer cobalt(III) complex. Angew. Chem. 1989, 101, (11), 1552-4.
  • Collins, T. J.; Gordon-Wylie, S. W., A manganese(V)-oxo complex. J. Am. Chem. Soc. 1989, 111, (12), 4511-13.
  • Collins, T. J.; Keech, J. T., Kinetics, mechanism, and thermodynamic aspects of the interconversion of complexes of planar and nonplanar metallo-amido-N-groups. J. Am. Chem. Soc. 1988, 110, (4), 1162-7.
  • Brewer, J. C.; Collins, T. J.; Smith, M. R.; Santarsiero, B. D., Neutral square planar cobalt(III) complexes. J. Am. Chem. Soc. 1988, 110, (2), 423-8.
  • Collins, T. J.; Ozaki, S.; Richmond, T. G., Catalytic oxidation of styrene in the presence of square planar cobalt(III) complexes of polyanionic chelating ligands. J. Chem. Soc., Chem. Commun. 1987, (11), 803-4.
  • Collins, T. J.; Lai, T.; Peake, G. T., A novel nonplanar amido-N ligand type. Nonplanarity in the amido-N ligand induced by steric effects. Inorg. Chem. 1987, 26, (11), 1674-7.
  • Anson, F. C.; Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Toth, J. E.; Treco, B. G. R. T., Highly stabilized copper(III) complexes. J. Am. Chem. Soc. 1987, 109, (10), 2974-9.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Krafft, T. E., Alcohol electrooxidation catalysts from degraded polyanionic chelating ligand complexes. The uncertainty for catalyst identification that accompanies a decomposing catalytic system. Inorg. Chem. 1987, 26, (5), 731-6.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Keech, J. T.; Krafft, T. E., Electrochemical studies of reactive polyanionic chelating ligand complexes in liquid sulfur dioxide. Formation of highly oxidizing inorganic complexes. Inorg. Chem. 1987, 26, (7), 1157-60.
  • Anson, F. C.; Collins, T. J.; Coots, R. J.; Gipson, S. L.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H., Oxidative and hydrolytic decomposition of a polyanionic chelating ligand. Inorg. Chem. 1987, 26, (7), 1161-8.
  • Collins, T. J.; Richmond, T. G.; Santarsiero, B. D.; Treco, B. G. R. T., Paramagnetic cobalt(III) complexes of polyanionic chelating ligands. J. Am. Chem. Soc. 1986, 108, (8), 2088-90.
  • Collins, T. J.; Coots, R. J.; Furutani, T. T.; Keech, J. T.; Peake, G. T.; Santarsiero, B. D., Nonplanar amide groups as ligands. J. Am. Chem. Soc. 1986, 108, (17), 5333-9.
  • Barner, C. J.; Collins, T. J.; Mapes, B. E.; Santarsiero, B. D., Reactions of osmium(IV) complexes of PAC ligands with azide species. Inorg. Chem. 1986, 25, (24), 4322-3.
  • Anson, F. C.; Collins, T. J.; Gipson, S. L.; Keech, J. T.; Krafft, T. E.; Peake, G. T., Interconversion of planar and nonplanar N-amido ligands. Thermodynamically stable nonplanar N-amido ligands. J. Am. Chem. Soc. 1986, 108, (21), 6593-605.
  • Christie, J. A.; Collins, T. J.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H., Complexation of a tetradentate tetraanionic ligand to osmium(IV): a step towards the development of multianionic chelating ligands for use in stabilizing oxidizing inorganic complexes. J. Chem. Soc., Chem. Commun. 1984, (3), 198-9.
  • Anson, F. C.; Collins, T. J.; Coots, R. J.; Gipson, S. L.; Richmond, T. G., Synthesis and characterization of stable cobalt(IV) coordination complexes: molecular structure of trans-[h4-1,2-bis(3,5-dichloro-2-hydroxybenzamido)-4,5-dichlorobenzene]bis(4-tert-butylpyridine)cobalt(IV). J. Am. Chem. Soc. 1984, 106, (17), 5037-8.
  • Anson, F. C.; Christie, J. A.; Collins, T. J.; Coots, R. J.; Furutani, T. T.; Gipson, S. L.; Keech, J. T.; Krafft, T. E.; Santarsiero, B. D.; Spies, G. H., The design of multianionic chelating ligands for the production of inorganic oxidizing agents. Osmium coordination chemistry that provides stable potent oxidizing agents and stable potent reducing agents. J. Am. Chem. Soc. 1984, 106, (16), 4460-72.