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Institute for Green Science, Carnegie Mellon return to homepage Carnegie Mellon Homepage

Publications

The Design of Catalysts for More Sustainable Chemistry

  • Popescu, D.-L.; Chanda, A.; Stadler, M. J.; Mondal, S.; Tehranchi, J.; Ryabov, A. D.; Collins, T. J., Mechanistically Inspired Design of Fe(III)TAML Peroxide-Activating Catalysts, J. Am. Chem. Soc. 2008, 130, (13), 4497-4506.
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  • Georgi, A.; Schierz, A.; Trommler, U.; Horwitz, C. P.; Collins, T. J.; Kopinke, F.-D., Activation of Hydrogen Peroxide by Complexes of Iron(III) with Humic Acid for Chemical Degradation of Organic Compounds in Water. Applied Catalysis B: Environmental 2006, in press.
  • Shappell Nancy, W.; Vrabel Melanie, A.; Madsen Peter, J.; Harrington, G.; Billey Lloyd, O.; Hakk, H.; Larsen Gerald, L.; Beach Evan, S.; Horwitz Colin, P.; Ro, K.; Hunt Patrick, G.; Collins Terrence, J., Destruction of estrogens using Fe-TAML/peroxide catalysis. Environ. Sci. Technol. 2008, 42, (4), 1296-300.
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  • Polshin, V.; Popescu, D.-L.; Fischer, A.; Chanda, A.; Horner, D. C.; Beach, E. S.; Henry, J.; Qian, Y.-L.; Horwitz, C. P.; Lente, G.; Fabian, I.; Muenck, E.; Bominaar, E. L.; Ryabov, A. D.; Collins, T. J., Attaining Control by Design over the Hydrolytic Stability of Fe-TAML Oxidation Catalysts. J. Am. Chem. Soc. 2008, 130, (13), 4497-4506.
  • Chahbane, N.; Lenoir, D.; Souabi, S.; Collins, T. J.; Schramm, K.-W., FeIII-TAML-catalyzed green oxidative decolorization of textile dyes in wastewater. Clean: Soil, Air, Water 2007, 35, (5), 459-464.
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  • Popescu, D.-L., Chanda, A., Stadler, M., Tiago de Oliveira, F., Ryabov, A. D., Münck, E., Bominaar, E. L., Collins, T. J., High-Valent First-Row Transition-Metal Complexes of Tetraamido (4N) and Diamidodialkoxido or Diamidophenolato (2N/2O) Ligands: Synthesis, Structure, and Magnetochemistry, Coord. Chem. Rev., 2007, 0000.
  • Tiago de Oliveira, F.; Chanda, A.; Banerjee, D.; Shan, X.; Mondal, S.; Que, L., Jr.; Bominaar, E. L.; Muenck, E.; Collins, T. J., Chemical and Spectroscopic Evidence for an FeV-Oxo Complex. Science (Washington, DC, U. S.) 2007, 315, (5813), 835-838.
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  • Mondal, S.; Hangun-Balkir, Y.; Alexandrova, L.; Link, D.; Howard, B.; Zandhuis, P.; Cugini, A.; Horwitz, C. P.; Collins, T. J., Oxidation of sulfur components in diesel fuel using Fe-TAML catalysts and hydrogen peroxide. Catal. Today 2006, 116, (4), 554-561.
  • Chanda, A.; Popescu, D.-L.; Tiago de Oliveira, F.; Bominaar, E. L.; Ryabov, A. D.; Muenck, E.; Collins, T. J., High-valent iron complexes with tetraamido macrocyclic ligands: Structures, Moessbauer spectroscopy, and DFT calculations. J. Inorg. Biochem. 2006, 100, (4), 606-619.
  • Chanda, A.; Khetan, S. K.; Banerjee, D.; Ghosh, A.; Collins, T. J., Total Degradation of Fenitrothion and Other Organophosphorus Pesticides by Catalytic Oxidation Employing Fe-TAML Peroxide Activators. J. Am. Chem. Soc. 2006, 128, (37), 12058-12059.
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  • Banerjee, D.; Markley, A. L.; Yano, T.; Ghosh, A.; Berget, P. B.; Minkley, E. G., Jr.; Khetan, S. K.; Collins, T. J., "Green" oxidation catalysis for rapid deactivation of bacterial spores. Angew. Chem., Int. Ed. 2006, 45, (24), 3974-3977.
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  • Naima Chahbane, Delia-Laura Popescu, Douglas A. Mitchell, Arani Chanda, Dieter Lenoir, Alexander D. Ryabov, Karl-Werner Schramm and Terrence J. Collins, Fe(III)–TAML-catalyzed green oxidative degradation of the azo dye Orange II by H2O2 and organic peroxides: products, toxicity, kinetics, and mechanisms, Green Chemistry 2006, 8, 1–10
  • Chanda, A.; Ryabov, A. D.; Mondal, S.; Alexandrova, L.; Ghosh, A.; Hangun-Balkir, Y.; Horwitz, C. P.; Collins, T. J., Activity-stability parameterization of homogeneous green oxidation catalysts. Chem.--Eur. J. 2006, 12, (36), 9336-9345.
  • Ghosh, A.; Tiago de Oliveira, F.; Yano, T.; Nishioka, T.; Beach Evan, S.; Kinoshita, I.; Munck, E.; Ryabov Alexander, D.; Horwitz Colin, P.; Collins Terrence, J., Catalytically active μ-Oxodiiron(IV) oxidants from Iron(III) and dioxygen. J. Am. Chem. Soc. 2005, 127, (8), 2505-13.
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  • Ghosh, A.; Ryabov Alexander, D.; Mayer Sherry, M.; Horner David, C.; Prasuhn Duane, E., Jr.; Sen Gupta, S.; Vuocolo, L.; Culver, C.; Hendrich Michael, P.; Rickard Cliffton, E. F.; Norman Richard, E.; Horwitz Colin, P.; Collins Terrence, J., Understanding the mechanism of H(+)-induced demetalation as a design strategy for robust iron(III) peroxide-activating catalysts. J. Am. Chem. Soc. 2003, 125, (41), 12378-9.
  • Ghosh, A.; Ryabov, A. D.; Mayer, S. M.; Horner, D. C.; Prasuhn, D.; Gupta, S. S.; Vuocolo, L.; Culver, C.; Hendrich, M. P.; Rickard, C. E. F.; Norman, R. E.; Horwitz, C. P.; Collins, T. J.; Controlling Acid-Induced Demetalation of Iron Peroxide-Activating Catalysts, J. Am. Chem. Soc. 2003, 125, 12378–12379.
    (download pdf)
  • Collins, T. J., TAML Oxidant Activators: A New Approach to the Activation of Hydrogen Peroxide for Environmentally Significant Problems. Acc. Chem. Res. 2002, 35, (9), 782-790.
  • Sen Gupta, S.; Stadler, M.; Noser, C. A.; Ghosh, A.; Steinhoff, B.; Lenoir, D.; Horwitz, C. P.; Schramm, K.-W.; Collins, T. J., Rapid total destruction of chlorophenols by activated hydrogen peroxide. Science (Washington, DC, U. S.) 2002, 296, (5566), 326-328.
    (full text) (abstract)
  • Ghosh, A.; Gupta, S. S.; Bartos, M. J.; Hangun, Y.; Vuocolo, L. D.; Steinhoff, B. A.; Noser, C. A.; Horner, D. A.; Mayer, S.; Inderhees, K.; Horwitz, C. P.; Spatz, J.; Ryabov, A. D.; Mondale, S.; and Collins, T. J.; Green chemistry. Sustaining a high-technology civilization, Pure Appl. Chem. 2001, 73, 113–118
  • Patterson, R. E.; Gordon-Wylie, S. W.; Woomer, C. G.; Norman, R. E.; Weintraub, S. T.; Horwitz, C. P.; Collins, T. J., Electron-Transfer Oxidation by Phase-Separating Reagents. Inorg. Chem. 1998, 37, (18), 4748-4750.
  • Miller, C. G.; Gordon-Wylie, S. W.; Horwitz, C. P.; Strazisar, S. A.; Peraino, D. K.; Clark, G. R.; Weintraub, S. T.; Collins, T. J., A Method for Driving O-Atom Transfer: Secondary Ion Binding to a Tetraamide Macrocyclic Ligand. J. Am. Chem. Soc. 1998, 120, (44), 11540-11541.
  • Horwitz, C. P.; Fooksman, D. R.; Vuocolo, L. D.; Gordon-Wylie, S. W.; Cox, N. J.; Collins, T. J., Ligand design approach for securing robust oxidation catalysts. J. Am. Chem. Soc. 1998, 120, (19), 4867-4868.
  • Collins, T. J.; Gordon-Wylie, S. W.; Bartos, M. J.; Horwitz, C. P.; Woomer, C. G.; Williams, S. A.; Patterson, R. E.; Vuocolo, L. D.; Paterno, S. A.; Strazisar, S. A.; Peraino, D. K.; Dudash, C. A., The design of green oxidants. Green Chem. 1998, 46-71.
  • Bartos, M.J.; Gordon-Wylie, S.W.; Fox, B.G.; Wright, L.J.; Weintraub, S.T.; Kauffmann, K.E.; Münck, E; Kostka, K. L.; Uffelman, E.S.; Rickard, C.E.F.; Noon, K.R.; Collins, T.J.; Designing Ligands to Achieve Robust Oxidation Catalysts, Coord. Chem. Rev. 1998, 174, 361–390.
  • T. J. Collins, Designing Ligands for Oxidizing Complexes, Accounts Chem. Res. 1994, 27, 279–285.
  • Collins, T.J.; Horwitz, C.P.; Gordon-Wylie, S.W.; Woomer, C.G.; Vuocolo, L.D.; Bartos, M.J.; Fooksman, D.; Strazisar, S.A.; Peraino, D.K.; Clark, G.R.; Weintraub, S.T.; The Development of Green Oxidants, Extented Abstract of Plenary Lecture, 1997 Green Chemistry and Engineering Conference, Implementing Vision 2020 for the Environment, National Academy of Sciences, Washington, D.C., June 23–25, 1997.
  • Collins, T.J.; Bartos, M.J.; Gordon-Wylie, S.W.; Fox, B.G.; Kauffmann, K.E.; Münck, E.; Rickard, C.E.F.; Weintraub, S.T.; Uffelman, E.S.; Wright, L.J.; Designing Ligands to Achieve Robust Atom-Transfer Oxidation Catalysts, J. Inorg. Biochem. 1995, 59, 318.